Modelling the degradation of acidic and alkaline printing paper
Auteur ou éditeur
Tétreault, Jean
Vedoy, Diogenes
Bégin, Paul
Lacombe, S. Paris
Dupont, Anne-Laurence
Date de publication
2023
Titre de la source
Cellulose
Résumé
There has always been an interest in the professional communities of libraries, archives and conservation science to find ways of estimating the rate of degradation of paper under archival conservation conditions. Previously we reported a number of considerations for developing a kinetic degradation model based on Whatman no.1 paper. In the present research, this model was extended to 10 different papers and validated. Various physical and chemical properties of acidic, neutral, and alkaline papers were measured, such as the degree of polymerization (DP), tensile strength, equilibrium moisture content, and pH, as well as alkaline fillers content when applicable. The activation energy (Ea) based on DP of cellulose and zero-span tensile strength were determined. Ea and pH had the most significant influence on the simulated decay of paper. Papers with a high Ea (> 120 kJ mol-1), alkaline such as those containing at least 2% CaCO3, and acidic—but good printing quality papers made of bleached chemical pulp– were found the most durable in ambient conditions. Papers with a lower Ea (< 110 kJ mol-1) such as lignocellulosic papers containing significant amount of mechanical pulp were much less stable over time. Whatman filter papers, used as models of pure cellulosic papers, were found to have low Ea despite the good quality cotton fibers. A generic isoperm equation based on Ea was developed to predict the changes in the state of papers under various climatic conditions, and was applicable independently of the pH of the paper. The model developed allows a better quantification of the deterioration rate of printing papers such as those that are currently, and will be in the future, found in our archival collections.
Langue
English = Anglais
Sujet
Paper - Conservation and restoration
Library materials - Conservation and restoration
Paper - Analysis
Papier - Conservation et restauration
Documents de bibliothèque - Conservation et restauration
